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Rate constants for the gas‐phase reactions of O 3 with selected organics at 296 K
Author(s) -
Atkinson Roger,
Aschmann Sara M.,
Fitz Dennis R.,
Winer Arthur M.,
Pitts James N.
Publication year - 1982
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550140103
Subject(s) - propene , chemistry , reaction rate constant , styrene , acrylonitrile , gas phase , molecule , xylene , hexene , propane , photochemistry , toluene , organic chemistry , ethylene , catalysis , kinetics , polymer , copolymer , physics , quantum mechanics
Rate constants for the gas‐phase reactions of O 3 with ethene, propene, 1‐hexene, 1‐heptene, styrene, o ‐, m ‐, and p ‐cresol, o ‐ and m ‐xylene, benzylchloride, acrylonitrile, and trichloroethene have been determined at 296 ± 2 K. The rate constants ranged from <5 × 10 −21 cm 3 molecule −1 s −1 for m ‐xylene to 2.16 × 10 −17 cm 3 molecule −1 s −1 for styrene, with those for ethene, propene, and 1‐hexene being in excellent agreement with literature data.