Infrared photochemistry of bis(trifluoromethyl) peroxide | Zendy

Francisco J. S. | Zendy; Findeis M. A. | Zendy; Steinfeld J. I. | Zendy

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Infrared photochemistry of bis(trifluoromethyl) peroxide

Author(s) -

Francisco J. S.,

Findeis M. A.,

Steinfeld J. I.

Publication year - 1981

Publication title -

international journal of chemical kinetics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.341

H-Index - 68

eISSN - 1097-4601

pISSN - 0538-8066

DOI - 10.1002/kin.550130704

Subject(s) - chemistry , trifluoromethyl , radical , photochemistry , peroxide , dissociation (chemistry) , infrared , photodissociation , excitation , organic chemistry , alkyl , physics , electrical engineering , optics , engineering

Bis(trifluoromethyl) peroxide is readily dissociated by multiple infrared photon excitation at CO 2 laser wavelengths. The primary dissociation product is CF 3 O; approximately 85% of the nascent radicals are further dissociated in the laser field to form CF 2 O and F. The F atoms then react with the remaining CF 3 O to produce CF 3 OF. The formation of CF 3 OF is strongly inhibited by addition of HI, which reacts preferentially with the F atoms.

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