The kinetics of radiation induced hydrogen abstraction by CCl 3  radicals in the liquid phase: Cyclanes | Zendy

Alfassi Zeev B. | Zendy; Feldman Liviu | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

The kinetics of radiation induced hydrogen abstraction by CCl 3 radicals in the liquid phase: Cyclanes

Author(s) -

Alfassi Zeev B.,

Feldman Liviu

Publication year - 1981

Publication title -

international journal of chemical kinetics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.341

H-Index - 68

eISSN - 1097-4601

pISSN - 0538-8066

DOI - 10.1002/kin.550130602

Subject(s) - chemistry , radical , cyclohexane , cyclooctane , kinetics , arrhenius equation , hydrogen atom abstraction , carbon tetrachloride , photochemistry , radiation chemistry , atmospheric temperature range , hydrogen , reaction rate constant , activation energy , organic chemistry , thermodynamics , chemical reaction , physics , quantum mechanics

The kinetics of gamma‐radiation induced free radicals reactions in carbon tetrachloride solutions of cyclohexane, cyclooctane and cyclododecane were studied in the range of 27–190°C. The activation energies found were in the order c C 6 H 12 > c C 12 H 24 > c C 8 H 16 , which was explained as due to their ring strain which has the same order. The following log k 1 was obtained using the known Arrhenius parameters for CCl 3 radical recombination:

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research