The determination of the arrhenius parameters for the reaction Cl + C 2 F 5 I → ICl + C 2 F 5  using a competitive method | Zendy

Ahonkhai Samuel I. | Zendy; Whittle Eric | Zendy

Premium

The determination of the arrhenius parameters for the reaction Cl + C 2 F 5 I → ICl + C 2 F 5 using a competitive method

Author(s) -

Ahonkhai Samuel I.,

Whittle Eric

Publication year - 1981

Publication title -

international journal of chemical kinetics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.341

H-Index - 68

eISSN - 1097-4601

pISSN - 0538-8066

DOI - 10.1002/kin.550130409

Subject(s) - chemistry , arrhenius equation , photodissociation , analytical chemistry (journal) , atmospheric temperature range , range (aeronautics) , thermodynamics , activation energy , photochemistry , chromatography , physics , materials science , composite material

The reactionshave been studied competitively over the range of 28–182°C by photolysis of mixtures of Cl 2 + C 2 F 5 I+ CH 4 . We obtain\documentclass{article}\pagestyle{empty}\begin{document}$$ \log {\rm }k_1 /k_2 = (0.96 \pm 0.06) + (1210 + 440)/\theta $$\end{document}where θ = 2.303 RT J/mol. The use of published data on reaction (2) leads to log ( k 1 cm 3 /mol sec) = (13.96 ± 0.2) − (11,500 ± 2000)/θ.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research