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On the effect of copper (II) and chloride ions on the iodate‐hydrogen peroxide reaction in the presence and absence of manganese (II)
Author(s) -
Cooke David O.
Publication year - 1980
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550121002
Subject(s) - chemistry , iodate , manganese , hydrogen peroxide , inorganic chemistry , copper , catalysis , chloride , peroxide , iodine , ion , iodide , organic chemistry
The effect of copper (II) and chloride ions on the manganese (II) catalyzed iodate‐peroxide reaction has been examined with reference to the hydrogen peroxide‐iodic acid‐manganese (II)‐organic species oscillatory reaction. The observations are considered to provide evidence for iodine dioxide as the key intermediate in the manganese (II) catalyzed reaction. Kinetic data for the copper (II) catalyzed reaction are reported.