Premium
The √ t law in solid‐phase reactions verification of the √ t law stability in h‐atom abstraction reactions
Author(s) -
Bol'shakov B. V.,
Stepanov A. A.,
Tolkatchev V. A.
Publication year - 1980
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550120408
Subject(s) - chemistry , alkyl , arrhenius equation , thermodynamics , abstraction , dimensionless quantity , annealing (glass) , computational chemistry , law , organic chemistry , activation energy , philosophy , physics , epistemology , political science
The law c = c 0 exp( K √t ) in the alkyl radical abstraction reaction is affected by neither the matrix annealing nor the way of the radical generation. If the reaction runs at varying temperature, a dimensionless time τ which does determine unambiguously the degree of conversion can be introduced.