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The rate constant for combination of a CCl 3 radical with cyclohexyl or n ‐hexyl radicals. An evidence for the value of the rate constant for a Cl atom transfer
Author(s) -
Alfassi Zeev B.
Publication year - 1980
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550120402
Subject(s) - chemistry , radical , cyclohexane , reaction rate constant , radiolysis , yield (engineering) , alkane , carbon tetrachloride , constant (computer programming) , alkyl , hexane , photochemistry , organic chemistry , thermodynamics , hydrocarbon , kinetics , physics , quantum mechanics , computer science , programming language
The variation of the radiolytic yield of hexachloroethane in the system alkane + carbon tetrachloride can be used to measure the rate constant for the combination of a CCl 3 radical with an alkyl radical. The treatment of the data for hexane and cyclohexane shows that the rate for a Cl atom transfer must be lower than the high values of Katz et al. and Tuan et al.