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Kinetic studies of free radical reactions by mass spectrometry. I. The reactions SO + NO 2 and ClO + NO
Author(s) -
Clyne Michael A. A.,
Macrobert Alexander J.
Publication year - 1980
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550120202
Subject(s) - chemistry , radical , kinetics , mass spectrometry , kinetic energy , photochemistry , impurity , free radical reaction , organic chemistry , chromatography , physics , quantum mechanics
A novel technique is described for forming ground‐state SO X 3 Σ radicals free of reactive impurities in a discharge‐flow system. Mass spectrometric detection of SO and ClO free radicals has been used to study the kinetics of the following reactions at 295 K: