Kinetic study of some elementary reactions of sulfur compounds including reactions of S and SO with OH radicals | Zendy

Jourdain J. L. | Zendy; Bras G. Le | Zendy; Combourieu J. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Kinetic study of some elementary reactions of sulfur compounds including reactions of S and SO with OH radicals

Author(s) -

Jourdain J. L.,

Bras G. Le,

Combourieu J.

Publication year - 1979

Publication title -

international journal of chemical kinetics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.341

H-Index - 68

eISSN - 1097-4601

pISSN - 0538-8066

DOI - 10.1002/kin.550110603

Subject(s) - chemistry , radical , reactivity (psychology) , electron paramagnetic resonance , sulfur , reaction rate constant , kinetic energy , analytical chemistry (journal) , kinetics , organic chemistry , nuclear magnetic resonance , pathology , quantum mechanics , medicine , physics , alternative medicine

The reactions of S + OH → SO + H (1) and SO + OH → SO 2 + H (2) were studied in a discharge flow reactor coupled to an EPR spectrometer. The rate constants obtained under the pseudo‐first‐order conditions with an excess of S or SO were found to be k 1 = (6.6 ± 1.4) × 10 −11 and k 2 = (8.4 ± 1.5) × 10 −11 at room temperature. Units are cm 3 /molec·sec. Besides no reactivity was observed between S and CO 2 at 298 K and between CIO and SO 2 up to 711 K.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research