Kinetics of fluorine atom reactions using resonance absorption spectrometry in the far vacuum ultraviolet reactions F + HCl, CH 4 , CHCl 3  CHCl 2 F, and CHClF 2 | Zendy

Clyne Michael A. A. | Zendy; Nip Wing S. | Zendy

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Kinetics of fluorine atom reactions using resonance absorption spectrometry in the far vacuum ultraviolet reactions F + HCl, CH 4 , CHCl 3 CHCl 2 F, and CHClF 2

Author(s) -

Clyne Michael A. A.,

Nip Wing S.

Publication year - 1978

Publication title -

international journal of chemical kinetics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.341

H-Index - 68

eISSN - 1097-4601

pISSN - 0538-8066

DOI - 10.1002/kin.550100404

Subject(s) - chemistry , fluorine , reaction rate constant , excited state , kinetics , resonance (particle physics) , absorption (acoustics) , branching (polymer chemistry) , analytical chemistry (journal) , chemical kinetics , mass spectrometry , branching fraction , photochemistry , atomic physics , organic chemistry , physics , quantum mechanics , chromatography , acoustics

Atomic resonance absorption spectrometry with a nonreversed fluorine resonance lamp (∼95 nm) has been used to study the kinetics of elementary reactions of ground state F 2 P J atoms in a discharge‐flow system. The following rate constants (in cm 3 /molec·sec) All rate constants are given with 1.5 σ. were determined at 298° K:The reaction F 2 P J + HCl(1) was found to give J‐excited Cl 2 P 1/2 atoms with a product branching ratio [Cl 2 P 1/2 ]/[Cl 2 P 3/2 ] = 0.10.

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