Kinetics of the thermal decomposition of bis‐pentafluorine sulfur peroxide in the presence of carbon monoxide | Zendy

Czarnowski J. | Zendy; Schumacher H. J. | Zendy

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Kinetics of the thermal decomposition of bis‐pentafluorine sulfur peroxide in the presence of carbon monoxide

Author(s) -

Czarnowski J.,

Schumacher H. J.

Publication year - 1978

Publication title -

international journal of chemical kinetics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.341

H-Index - 68

eISSN - 1097-4601

pISSN - 0538-8066

DOI - 10.1002/kin.550100109

Subject(s) - chemistry , carbon monoxide , thermal decomposition , torr , decomposition , kinetics , partial pressure , sulfur , total pressure , homogeneous , reaction mechanism , chemical decomposition , peroxide , reaction rate constant , inorganic chemistry , thermodynamics , organic chemistry , catalysis , oxygen , physics , quantum mechanics

The thermal decomposition of F 5 SOOSF 5 , P, in the presence of CO has been investigated between 130.1° and 161.9°C at total pressures between 50 and 600 torr. The reaction is homogeneous, and the only final products formed are CO 2 and S 2 F 10 . The rate of reaction is proportional to the pressure of P. The partial pressures of CO and O 2 and the total pressure have no influence on the course of reaction:\documentclass{article}\pagestyle{empty}\begin{document}$$ - \frac{{d\left[P \right]}}{{dt}} = k\left[P \right] $$\end{document}The results are explained by the following mechanism:

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