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Kinetics of the thermal decomposition of bis‐pentafluorine sulfur peroxide in the presence of carbon monoxide
Author(s) -
Czarnowski J.,
Schumacher H. J.
Publication year - 1978
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550100109
Subject(s) - chemistry , carbon monoxide , thermal decomposition , torr , decomposition , kinetics , partial pressure , sulfur , total pressure , homogeneous , reaction mechanism , chemical decomposition , peroxide , reaction rate constant , inorganic chemistry , thermodynamics , organic chemistry , catalysis , oxygen , physics , quantum mechanics
The thermal decomposition of F 5 SOOSF 5 , P, in the presence of CO has been investigated between 130.1° and 161.9°C at total pressures between 50 and 600 torr. The reaction is homogeneous, and the only final products formed are CO 2 and S 2 F 10 . The rate of reaction is proportional to the pressure of P. The partial pressures of CO and O 2 and the total pressure have no influence on the course of reaction:\documentclass{article}\pagestyle{empty}\begin{document}$$ - \frac{{d\left[P \right]}}{{dt}} = k\left[P \right] $$\end{document}The results are explained by the following mechanism: