Reaction between nitrous acid and hydrogen peroxide in perchloric acid medium | Zendy

Bhattacharyya P. K. | Zendy; Veeraraghavan R. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Reaction between nitrous acid and hydrogen peroxide in perchloric acid medium

Author(s) -

Bhattacharyya P. K.,

Veeraraghavan R.

Publication year - 1977

Publication title -

international journal of chemical kinetics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.341

H-Index - 68

eISSN - 1097-4601

pISSN - 0538-8066

DOI - 10.1002/kin.550090411

Subject(s) - chemistry , nitrous acid , perchloric acid , hydrogen peroxide , reaction rate constant , activation energy , kinetic energy , equilibrium constant , reaction rate , inorganic chemistry , analytical chemistry (journal) , thermodynamics , kinetics , organic chemistry , catalysis , physics , quantum mechanics

A kinetic investigation on the reactionhas been carried out in HClO 4 medium under different conditions. A spectrophotometric method of estimation of nitrous acid at various time intervals has been employed. The results are interpreted on the basis ofthe following mechanism:The absolute rate constant value of 39.7 M −1 plusmn; s −1 for k 4 and the equilibrium constant K eq = 116 M −1 for reaction (2) have been evaluated. The activation energy of the overall reaction has also been determined as E a = 13.2 kcal/mol.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research