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Kinetics of the Fe 3+ ion–H 2 O 2 reaction: Steady‐state and terminal‐state analysis
Author(s) -
Kremer Mordechai L.,
Stein Gabriel
Publication year - 1977
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550090203
Subject(s) - chemistry , kinetics , terminal (telecommunication) , decomposition , ion , steady state (chemistry) , chemical reaction kinetics , ferric , catalysis , state (computer science) , chemical kinetics , stereochemistry , inorganic chemistry , physics , organic chemistry , telecommunications , quantum mechanics , computer science , algorithm
Computer calculations of the kinetics of the ferric ion catalyzed decomposition of H 2 O 2 by Walling and Weil are not in contradiction to the “complex mechanism.” The examination of their results reveals that their simulations correspond to the terminal state of the system in which the secondary complex between Fe 3+ and H 2 O 2 becomes stabilized.