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Flash photolysis study of the recombination of chlorine atoms in the presence of various inert gases and NO
Author(s) -
Hippler H.,
Troe J.
Publication year - 1976
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550080404
Subject(s) - chemistry , chlorine , flash photolysis , recombination , chlorine atom , inert , photodissociation , inert gas , photochemistry , flash (photography) , kinetics , medicinal chemistry , reaction rate constant , organic chemistry , art , biochemistry , physics , quantum mechanics , visual arts , gene
The recombination of chlorine atoms has been investigated by flash photolysis in the inert gases He, Ne, Ar, N 2 , CO 2 , CF 4 , SiF 4 , SF 6 , and C 2 F 6 . The pressure dependence of the reaction has been measured between 0.5 and about 100 atm for He, N 2 , and CO 2 . Experiments on the NO‐catalyzed recombination of chlorine in the presence of He (0.5–100 atm) permitted a determination of the falloff curve of the reaction Cl+NO(+He)→ClNO(+He).