Flash photolysis study of the recombination of chlorine atoms in the presence of various inert gases and NO | Zendy

Hippler H. | Zendy; Troe J. | Zendy

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Flash photolysis study of the recombination of chlorine atoms in the presence of various inert gases and NO

Author(s) -

Hippler H.,

Troe J.

Publication year - 1976

Publication title -

international journal of chemical kinetics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.341

H-Index - 68

eISSN - 1097-4601

pISSN - 0538-8066

DOI - 10.1002/kin.550080404

Subject(s) - chemistry , chlorine , flash photolysis , recombination , chlorine atom , inert , photodissociation , inert gas , photochemistry , flash (photography) , kinetics , medicinal chemistry , reaction rate constant , organic chemistry , art , biochemistry , physics , quantum mechanics , visual arts , gene

The recombination of chlorine atoms has been investigated by flash photolysis in the inert gases He, Ne, Ar, N 2 , CO 2 , CF 4 , SiF 4 , SF 6 , and C 2 F 6 . The pressure dependence of the reaction has been measured between 0.5 and about 100 atm for He, N 2 , and CO 2 . Experiments on the NO‐catalyzed recombination of chlorine in the presence of He (0.5–100 atm) permitted a determination of the falloff curve of the reaction Cl+NO(+He)→ClNO(+He).

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