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Thermal decomposition of trimethylene sulfone and 3‐methyl sulfolane
Author(s) -
Cornell Douglas,
Tsang W.
Publication year - 1975
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550070602
Subject(s) - sulfolane , sulfone , chemistry , thermal decomposition , toluene , pyrolysis , decomposition , chemical decomposition , organic chemistry , polymer chemistry , solvent
Trimethylene sulfone and 3methyl sulfolane have been pyrolyzed using a modification of the toluene flow method and a comparative rate technique. The main decomposition reactions arewhere k 1 =10 16.1±0.3 exp(−28,100±500/ T ) sec −1 and k 2 =10 16.1±0.4 exp(−33,200±750/ T ) sec −1 .