Premium
Yet another direct measurement of the rate constant for the recombination of methyl radicals
Author(s) -
James F. C.,
Simons J. P.
Publication year - 1974
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550060611
Subject(s) - chemistry , radical , recombination , reaction rate constant , photoelectric effect , spectrometer , kinetic energy , recombination rate , absorption (acoustics) , photochemistry , analytical chemistry (journal) , atomic physics , kinetics , optics , organic chemistry , physics , biochemistry , quantum mechanics , gene
Abstract The decaying absorption of CH 3 radicals at 216.4 nm has been followed over more than three half‐lives using a photoelectric split‐beam kinetic spectrometer. The rate constant for recombination k r was found to be (5.60 ± 0.76) × 10 −11 cm 3 /molecule·s.