Yet another direct measurement of the rate constant for the recombination of methyl radicals | Zendy

James F. C. | Zendy; Simons J. P. | Zendy

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Yet another direct measurement of the rate constant for the recombination of methyl radicals

Author(s) -

James F. C.,

Simons J. P.

Publication year - 1974

Publication title -

international journal of chemical kinetics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.341

H-Index - 68

eISSN - 1097-4601

pISSN - 0538-8066

DOI - 10.1002/kin.550060611

Subject(s) - chemistry , radical , recombination , reaction rate constant , photoelectric effect , spectrometer , kinetic energy , recombination rate , absorption (acoustics) , photochemistry , analytical chemistry (journal) , atomic physics , kinetics , optics , organic chemistry , physics , biochemistry , quantum mechanics , gene

The decaying absorption of CH 3 radicals at 216.4 nm has been followed over more than three half‐lives using a photoelectric split‐beam kinetic spectrometer. The rate constant for recombination k r was found to be (5.60 ± 0.76) × 10 −11 cm 3 /molecule·s.

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