The solvent‐jump relaxation method using continuous flow | Zendy

Schelly Z. A. | Zendy; Wong M. M. | Zendy

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The solvent‐jump relaxation method using continuous flow

Author(s) -

Schelly Z. A.,

Wong M. M.

Publication year - 1974

Publication title -

international journal of chemical kinetics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.341

H-Index - 68

eISSN - 1097-4601

pISSN - 0538-8066

DOI - 10.1002/kin.550060506

Subject(s) - chemistry , jump , solvent , temperature jump , relaxation (psychology) , aqueous solution , amplitude , rhodamine b , rhodamine , volumetric flow rate , analytical chemistry (journal) , thermodynamics , chromatography , organic chemistry , fluorescence , optics , physics , psychology , social psychology , quantum mechanics , photocatalysis , catalysis

A step perturbation (concentration‐jump or solvent‐jump) relaxation method is described for studying the rates of fast reactions, using nontransient observation in a steadystate flow system. Therelaxation time is determined from a single measurement of an integrated relaxation amplitude. Remeasurement of the rate of dimerization of aqueous rhodamine B is reported.

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