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Recalculation of data on the thermal decomposition of 1,1‐difluoroethane and 1,1,1‐trifluoroethane
Author(s) -
Tsang Wing
Publication year - 1973
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550050414
Subject(s) - chemistry , thermal decomposition , decomposition , thermodynamics , reaction rate constant , thermal , organic chemistry , kinetics , physics , classical mechanics
Disagreements in rate constants and parameters between published results on the decomposition of 1,1‐difluoroethane and 1,1,1‐trifluoroethane are shown to originate from incorrect specification and setting of reaction conditions in one of the studies. When corrected, applicable results are in excellent agreement.