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Investigation of the rate coefficient for O( 3 p ) + NO 2 → O 2 + NO
Author(s) -
Slanger Tom G.,
Wood Bernard J.,
Black Graham
Publication year - 1973
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550050411
Subject(s) - chemistry , analytical chemistry (journal) , chromatography
Measurements of the rate coefficient of the reaction (O 3 P ) + NO 2 → O 2 + NO have been made at 296°K and 240°K, using the technique of NO 2 * chemiluminescent decay. Values of 9.3 × 10 −12 cm 3 molec −1 sec −1 at 296°K and 10.5 × 10 −12 cm 3 molec −1 sec −1 at 240°K were obtained, in excellent agreement with the recent results of Davis, Herron, and Huie [1]. The earlier lower values may have resulted from loss of NO 2 on surfaces.