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Deactivation of vibrationally excited hydrogen fluoride ( v =2 and v =1) by atomic fluorine
Author(s) -
Blauer Jay A.,
Solomon Wayne C.
Publication year - 1973
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550050406
Subject(s) - chemistry , fluorine , excited state , hydrogen fluoride , reaction rate constant , hydrogen , atomic physics , fluoride , inorganic chemistry , kinetics , organic chemistry , physics , quantum mechanics
Measurements have been made which provide information concerning the rate of energy transfer between vibrationally excited HF and atomic fluorine. It was found that HF ( v = 1) deactivates about seven times slower than was determined in previous experiments. The deactivation rate constant for HF ( v = 2) is about six times larger than for HF ( v = 1).