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Liquid‐phase hydrogen abstraction from chlorinated ethanes by chlorine atoms
Author(s) -
Martens G. J.,
Franklin J. A.,
Godfroid M.,
Delvaux M.,
Verbeyst J.
Publication year - 1973
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550050404
Subject(s) - chemistry , chlorine atom , chlorine , hydrogen atom abstraction , abstraction , chloroform , hydrogen , gas phase , phase (matter) , liquid phase , reaction rate constant , computational chemistry , photochemistry , organic chemistry , inorganic chemistry , thermodynamics , medicinal chemistry , kinetics , philosophy , physics , epistemology , quantum mechanics
The hydrogen abstraction from the chlorinated ethanes by chlorine atoms has been investigated in the liquid phase. Rate constants relative to that for hydrogen abstraction from chloroform have been measured between 267° and 333°K using a competition technique. The results are compared with gas‐phase data.