Kinetics of the reactions of cyclopropane derivatives. IV. Kinetic isotope effect in the isomerisation of cyclopropylamine | Zendy

Luckraft D. A. | Zendy; Robinson P. J. | Zendy

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Kinetics of the reactions of cyclopropane derivatives. IV. Kinetic isotope effect in the isomerisation of cyclopropylamine

Author(s) -

Luckraft D. A.,

Robinson P. J.

Publication year - 1973

Publication title -

international journal of chemical kinetics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.341

H-Index - 68

eISSN - 1097-4601

pISSN - 0538-8066

DOI - 10.1002/kin.550050303

Subject(s) - chemistry , isomerization , kinetic isotope effect , cyclopropane , kinetic energy , kinetics , amine gas treating , hydrogen isotope , hydrogen , deuterium , computational chemistry , photochemistry , organic chemistry , catalysis , ring (chemistry) , physics , quantum mechanics

The high‐pressure isotopic rate ratio k H / k D for isomerisation of cyclopropylamine and cyclopropylamine‐N‐ d 2 is 1.06 at 649–678 K, supporting a mechanism which does not involve migration of hydrogen from the amine group in the rate‐determining step.

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