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Rates of reaction of atomic oxygen with C 2 H 3 F, C 2 H 3 Cl, C 2 H 3 Br, 1,1‐C 2 H 2 F 2 , and 1,2‐C 2 H 2 F 2
Author(s) -
Huie Robert E.,
Herron John T.,
Davis Douglas D.
Publication year - 1972
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550040506
Subject(s) - chemistry , halide , reaction rate constant , oxygen , atomic oxygen , analytical chemistry (journal) , mass spectrometry , medicinal chemistry , inorganic chemistry , kinetics , organic chemistry , physics , quantum mechanics , chromatography
Rate constants for the reactions of atomic oxygen (O 3 P ) with C 2 H 3 F, C 2 H 3 Cl, C 2 H 3 Br, 1,1‐C 2 H 2 F 2 , and 1,2‐C 2 H 2 F 2 have been measured at 307°K using a discharge‐flow system coupled to a mass spectrometer. The rate constants for these reactions are (in units of 10 11 cm 3 mole −1 s −1 ) 2.63 ± 0.38, 5.22 ± 0.24, 4.90 ± 0.34, 2.19 ± 0.18, and 2.70 ± 0.34, respectively. For some of these reactions, the product carbonyl halides were identified.
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