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Kinetics of the thermal gas phase reactions of 1,2‐epoxy‐2‐methylpropane
Author(s) -
Flowers M. C.,
Parker R. M.
Publication year - 1971
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550030506
Subject(s) - isobutyraldehyde , chemistry , kinetics , isomerization , thermal decomposition , epoxide , decomposition , torr , homogeneous , epoxy , photochemistry , atmospheric temperature range , gas phase , ether , organic chemistry , thermodynamics , catalysis , physics , quantum mechanics
Abstract The kinetics of the gas phase decomposition of 1,2‐epoxy‐2‐methylpropane has been studied over the temperature range 377°–436°C at pressures between 5.3 and 61.6 torr. Isomerization reactions to give isobutyraldehyde, isopropenyl methyl ether, and 2‐methyl‐prop‐2‐en‐l‐ol account for over 95% of the epoxide decomposition. These isomerizations are homogeneous first‐order, nonradical processes:\documentclass{article}\pagestyle{empty}\begin{document}$$\begin{array}{l} k({\rm isobutyraldehyde)} = {\rm 10}^{{\rm 13}{\rm .32} \pm {\rm 0}{\rm .18}} \exp (- 52720 \pm 570/1.987T)\sec ^{- 1} \\ {\rm}k({\rm isopropenyl methyl ether)} = {\rm 10}^{{\rm 13}{\rm .55} \pm {\rm 0}{\rm .47}} \exp (- 56140 \pm 1460/1.987T)\sec ^{- 1} \\ {\rm}k({\rm 2 - methyl - prop - 2 - en - l - ol)} = {\rm 10}^{{\rm 11}{\rm .53} \pm {\rm 0}{\rm .67}} \exp (- 49680 \pm 2080/1.987T)\sec ^{- 1} \\ \end{array}$$\end{document}