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Mechanism of the oscillating chemiluminescence reaction in the luminol‐H 2 O 2 ‐KSCN‐CuSO 4 ‐NaOH system
Author(s) -
Toki Erika,
Osaki Shiori,
Nakamura Misato,
Tsuoka Kazuki,
Samejima Nobutoshi,
Nakashima Tetsuto,
Abe Rin,
Oyama Takahiro,
Tsukiyama Koichi
Publication year - 2020
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.21409
Subject(s) - chemiluminescence , chemistry , luminol , redox , oscillation (cell signaling) , reaction mechanism , analytical chemistry (journal) , photochemistry , inorganic chemistry , catalysis , chromatography , organic chemistry , biochemistry
We conducted a simultaneous measurement of the potential of Cu 2+ , oxidation‐reduction potential (ORP), and the chemiluminescence intensity in the luminol‐H 2 O 2 ‐KSCN‐CuSO 4 ‐NaOH system. Two types of chemiluminescence were identified: a very faint continuous chemiluminescence and a strong oscillating chemiluminescence. The correlation between the potential of Cu 2+ and ORP was measured experimentally for the first time. The effect of the initial concentrations of Cu 2+ and H 2 O 2 on the overall chemiluminescence intensity and the oscillation frequency was investigated in detail. Time‐dependent concentration variation of the chemical species existing in the reaction system was calculated using a Runge‐Kutta method. Two elementary chemical reactions not considered previously were taken into consideration. The overall experimental behavior was well explainable with our simulation. Based upon the comparison of our simulation with the experiment, we proposed that the strong oscillating chemiluminescence was induced by the reaction of luminol with ·OS(O)CN.