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Dissolution optimization and kinetics of nickel and cobalt from iron‐rich laterite ore, using sulfuric acid at atmospheric pressure
Author(s) -
Hosseini Nasab Marzieh,
Noaparast Mohammad,
Abdollahi Hadi
Publication year - 2020
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.21349
Subject(s) - laterite , cobalt , nickel , chemistry , calcination , leaching (pedology) , sulfuric acid , cobalt extraction techniques , dissolution , nuclear chemistry , metallurgy , inorganic chemistry , catalysis , materials science , soil water , geology , biochemistry , organic chemistry , soil science
More than 70% of the world's nickel reserves are found in laterite ores. In this research, a laterite ore sample, containing Ni, Co, and Fe, was employed to study the recovery of nickel and cobalt. Thus, the effect of calcination, acid concentration, percent solids, and stirring rate on nickel and cobalt recoveries from an iron‐rich laterite sample was investigated. Optimization with response surface methodology and kinetic studies were performed. The calcination of the sample prior to leaching at 500°C for 2 h provided condition for better nickel and cobalt dissolutions. At optimal conditions, the concentration of sulfuric acid, solid‐to‐liquid ratio, stirring speed, temperature, and time test were equal to 5 M, 0.1, 370 rpm, 90°C, and 2 h, respectively. The highest recoveries of nickel and cobalt were 65.9% and 63.1%, respectively. Solids content had a negative effect on Ni and Co recovery, whereas acid concentration was positively affected. Addition of 10% (w/v) NaCl in the presence of 5 M acid concentration, 60°C, 370 rpm, and leaching time of 2 h increased the nickel and cobalt recoveries, 15.3% and 21.4%, respectively. The high dependence of process on temperature indicates chemical control; the activation energies E a = 59.54 and E a = 45.74 kJ/mol, respectively, for nickel and cobalt, were also consistent with this conclusion.