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Synthesis of high added value compounds through catalytic oxidation of 2‐phenylethanol: A Kinetic study
Author(s) -
Ben Hmida Rania,
Frikha Nourzed,
Bouguerra Neji Soumaya,
Kit Geoffrey,
Medina Francisco,
Bouaziz Mohamed
Publication year - 2020
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.21336
Subject(s) - tyrosol , chemistry , hydrogen peroxide , hydroxytyrosol , catalysis , dpph , organic chemistry , antioxidant , peroxide , nuclear chemistry , polyphenol
An effective procedure was developed to produce high‐value added phenolic compounds through the conversion of 2‐phenylethanol (2‐PhEt) by using acid‐activated clays KSF for the hydrogen peroxide. Owing to KSF's ability to catalyze a variety of complex oxidations, it was likely to convert 2‐PhEt to hydroxytyrosol (HTY) and tyrosol (TY) derivatives. The analyses of catalytic solution revealed that the optimum conditions, giving a higher concentration of oxidation products such as HTY, were as follows: 2‐PhEt concentration 10 −2 mol/L, the hydrogen peroxide concentration 5.05 × 10 −2 and 0.6 g L –1 of KSF clays . The yield during the conversion reaction into HTY was around 25%. All compounds in the reaction mixture were identified by mass spectrophotometry using a LC‐MS apparatus. HTY, TY, meta ‐tyrosol and ortho ‐tyrosol were the major compounds. The antioxidant activity was realized by 2,2‐diphenyl‐1‐picrylhydrazyl (DPPH) method. In fact, it is revealed that the strongest inhibition percentage (PI = 96) was detected with the increase in the concentration of HTY. The approach proposed in the present work presents an environment friendly method.