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Kinetic study of the reaction of nucleophilic cyclopropanation of C 60 fullerene with halogenated maleopimarimide
Author(s) -
Biglova Yulya N.,
Malikova Rauilya N.,
Petrova Svetlana F.,
Ivanov Sergey P.,
Sakhautdinov Ilshat M.,
Mustafin Akhat G.
Publication year - 2019
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.21254
Subject(s) - cyclopropanation , chemistry , nucleophile , fullerene , yield (engineering) , kinetics , kinetic energy , diterpene , organic chemistry , medicinal chemistry , catalysis , thermodynamics , physics , quantum mechanics
The kinetics of nucleophilic fullerene cyclopropanation by halomethyl ketones with a diterpene fragment has been studied by the Bingel method, and the influence of the biologically active cyclopropanating agent on the process has been estimated. It has been revealed that favorable conditions for carrying out the reaction result in maximum monofunctionalized methanofullerenes formation with the maximum yield.