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Determination of Polyurethane Foam Growth Kinetics by a Simple Column Height Test
Author(s) -
Saavedra Oscar Arciniega,
Fadrique Jesús Gracia
Publication year - 2015
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.20961
Subject(s) - polyurethane , isocyanate , chemistry , kinetics , polypropylene glycol , kinetic energy , work (physics) , diffusion , thermodynamics , polymerization , polypropylene , blowing agent , polymer chemistry , chemical engineering , polymer , organic chemistry , polyethylene glycol , physics , quantum mechanics , engineering
In the present work, the height of foam column has been used to monitor the reaction of the isocyanate group. Kinetic modeling describes the conversion versus time curves. The global reaction can be divided into two different paths: the blowing reaction and the polymerization. The kinetics of the reaction of toluene diisocyanate with a polypropylene glycol has been studied with auxiliary blowing agents; the concentration of NCO and OH groups could be considered equivalent during all the experiments as a model for similar polyurethane systems. Despite the complexity of the system in which different kinetic orders are possible, as well a physically controlled diffusion process, data were fitted to a simple kinetic model of an apparent order. The results obtained have enabled us to propose a reaction path and catalyzed second‐order kinetic model.