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Oxidation and Destruction of Polyvinyl Alcohol in the Aqueous Phase
Author(s) -
Zimin Yu. S.,
Borisov I. M.,
Borisova N. S.,
Mustafin A. G.
Publication year - 2013
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.20820
Subject(s) - polyvinyl alcohol , chemistry , hydrogen peroxide , aqueous solution , oxygen , ozone , alcohol , peroxide , aqueous two phase system , polymer , phase (matter) , polymer chemistry , photochemistry , organic chemistry
We have studied kinetic laws of polyvinyl alcohol oxidation under the action of an ozone–oxygen mixture and hydrogen peroxide in an aqueous medium. It is shown that polymer oxidation is carried out by the radical mechanism. The scheme of oxidative transformations of polyvinyl alcohol explaining the obtained results is suggested.