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Synthesis of polyetherols with purine ring. Kinetics and mechanisms of reactions, part 1: Reaction of hydroxymethyl derivatives of uric acid with oxiranes
Author(s) -
CisekCicirko Irmina,
Lubczak Jacek
Publication year - 2005
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.20098
Subject(s) - chemistry , hydroxymethyl , uric acid , kinetics , purine , formaldehyde , ring (chemistry) , catalysis , medicinal chemistry , organic chemistry , biochemistry , physics , quantum mechanics , enzyme
The kinetics and mechanisms of the initial steps of formation of polyetherols from hydroxymethyl derivatives of uric acid and oxiranes were studied. It has been found that initial steps of the reaction of polyetherol formation occur without a catalyst. The NH groups, which are formed upon release of formaldehyde from N ‐ and O ‐hydroxymethyl derivatives of uric acid, take part in the reaction. © 2005 Wiley Periodicals, Inc. Int J Chem Kinet 37: 464–471, 2005