Liquid‐phase oxidation of 1‐isopropyl‐ and 1‐ethyl‐4‐methoxybenzenes with oxygen to hydroperoxides | Zendy

Zawadiak Jan | Zendy; Stec Zbigniew | Zendy; Jakubowski Bartłomiej | Zendy; Orlińska Beata | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Liquid‐phase oxidation of 1‐isopropyl‐ and 1‐ethyl‐4‐methoxybenzenes with oxygen to hydroperoxides

Author(s) -

Zawadiak Jan,

Stec Zbigniew,

Jakubowski Bartłomiej,

Orlińska Beata

Publication year - 2002

Publication title -

international journal of chemical kinetics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.341

H-Index - 68

eISSN - 1097-4601

pISSN - 0538-8066

DOI - 10.1002/kin.10108

Subject(s) - chemistry , isopropyl , yield (engineering) , oxygen , kinetics , atmospheric temperature range , liquid phase , ethyl ester , thermal stability , phase (matter) , ethyl acetate , organic chemistry , medicinal chemistry , thermodynamics , physics , quantum mechanics

A study was carried out on the kinetics of free‐radical chain oxidation of 1‐isopropyl‐4‐methoxybenzene ( 1a ) and 1‐ethyl‐4‐methoxybenzene ( 1b ) with oxygen in the liquid phase to yield 1‐methyl‐1‐(4‐methoxyphenyl)ethyl hydroperoxide ( 2a ) and 1‐(4‐methoxyphenyl)ethyl hydroperoxide ( 2b ). The oxidizability of 1a and 1b was studied over the temperature range 50–100°C. Long‐term oxidations of 1a and 1b to the corresponding hydroperoxides were carried out and the properties and thermal stability of 2a were established. © 2002 Wiley Periodicals, Inc. Int J Chem Kinet 35: 89–94, 2003

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research