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Preparation and characterization of molecularly imprinted polymers based on β‐cyclodextrin‐stabilized Pickering emulsion polymerization for selective recognition of erythromycin from river water and milk
Author(s) -
Li Tianhao,
Li Xiufang,
Liu Hui,
Deng Zhiwei,
Zhang Yunshan,
Zhang Zhuomin,
He Yao,
Yang Yanjing,
Zhong Shian
Publication year - 2020
Publication title -
journal of separation science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.72
H-Index - 102
eISSN - 1615-9314
pISSN - 1615-9306
DOI - 10.1002/jssc.201901255
Subject(s) - molecularly imprinted polymer , adsorption , polymer , chemistry , langmuir adsorption model , precipitation polymerization , molecular imprinting , polymerization , cyclodextrin , pickering emulsion , selective adsorption , emulsion polymerization , emulsion , chromatography , chemical engineering , selectivity , organic chemistry , radical polymerization , catalysis , engineering
Molecularly imprinted polymers were prepared via β‐cyclodextrin‐stabilized oil‐in‐water Pickering emulsion polymerization for selective recognition and adsorption of erythromycin. The synthesized molecularly imprinted polymers were spherical in shape, with diameters ranging from 20 to 40 µm. The molecularly imprinted polymers showed high adsorption capacity (87.08 mg/g) and adsorption isotherm data fitted well with Langmuir model. Adsorption kinetics study demonstrated that the molecularly imprinted polymers acted in a fast adsorption kinetic pattern and the adsorption features of molecularly imprinted polymers followed a pseudo‐first‐order model. Adsorption selectivity analysis revealed that molecularly imprinted polymers had a much better specificity for erythromycin than that for spiramycin or amoxicillin, and the relative selectivity coefficient values on the bases of spiramycin and amoxicillin were 3.97 and 3.86, respectively. The Molecularly imprinted polymers also showed a satisfactory reusability after four times of regeneration. In addition, molecularly imprinted polymers exhibited good adsorption capacities for erythromycin under complicated environment, that is, river water and milk. These results proved that the as‐prepared molecularly imprinted polymers is a potent absorbent for selective recognition of erythromycin, and therefore it may be a promising candidate for practical applications, such as wastewater treatment and detection of erythromycin residues in food.