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Application of high‐surface‐area graphitized carbon black with primary secondary amine as an alternative quick, easy, cheap, effective, rugged, and safe cleanup material for pesticide multi‐residue analysis in spinach
Author(s) -
Islam Abul Kasem Mohammad Mydul,
Lee HyoSub,
Ro JinHo,
Kim Danbi,
Kwon Hyeyoung
Publication year - 2019
Publication title -
journal of separation science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.72
H-Index - 102
eISSN - 1615-9314
pISSN - 1615-9306
DOI - 10.1002/jssc.201900066
Subject(s) - sorbent , solid phase extraction , chromatography , chemistry , sample preparation , extraction (chemistry) , calibration curve , matrix (chemical analysis) , carbon black , detection limit , residue (chemistry) , materials science , adsorption , organic chemistry , natural rubber
A multi‐residue method has been developed and validated to determine 46 pesticides in spinach using liquid chromatography tandem mass spectrometry. The method is based on modified quick, easy, cheap, effective, rugged, and safe sample preparation, where high‐surface‐area graphitized carbon black was used first as sorbent material in the dispersive solid‐phase extraction. The method was compared with the quick, easy, cheap, effective, rugged, and safe method. The morphology, surface area, pore size, and pore volume of the sorbent was determined. The results obtained show that the sorbent consists of high surface area (233 m 2 /g) and large pore volume (1.5 cm 3 /g). The calibration curve correlation coefficient ( R 2 ) of the method was at least 0.99. The average recoveries ranged from 74 to 116%, and limits of detection and quantification from 0.0001 to 0.002 mg/kg and from 0.0002 to 0.005 mg/kg, respectively. Using the method, the pesticides exhibited low matrix effect (< 20%), except for nicosulfuron (29.86%), methomyl (26.77%), and flufenoxuron (24.65%). The method showed better potential to remove pigments than the quick, easy, cheap, effective, rugged, and safe method. It is demonstrated that the proposed method could be useful alternative for sample preparation of spinach and other matrices in future.