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Some theoretical considerations on preparative separation with orthogonal pressurised planar electrochromatography
Author(s) -
Gajos Rafał,
Polak Beata,
Dzido Tadeusz H.
Publication year - 2019
Publication title -
journal of separation science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.72
H-Index - 102
eISSN - 1615-9314
pISSN - 1615-9306
DOI - 10.1002/jssc.201800720
Subject(s) - electrochromatography , capillary electrochromatography , planar , separation (statistics) , chromatography , separation method , materials science , chemistry , computer science , stationary phase , computer graphics (images) , machine learning
In this work, separation of multicomponent mixtures containing components with the same and different electrophoretic mobility by using orthogonal pressurised planar electrochromatography is studied theoretically. Additionally, a simple way for determination of a maximum amount of mixture causing volume overload of flat/planar columns used in this technique is presented. In the next stage, effects of change in different parameters on process performance by simulation case studies are investigated. A comparative study of separation productivity of orthogonal pressurised planar electrochromatography with the continuous and periodic modes of mixture delivery and column chromatography is carried out.