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Preparation and applications of monolithic structures containing metal–organic frameworks
Author(s) -
Lv Yongqin,
Tan Xinyi,
Svec Frantisek
Publication year - 2017
Publication title -
journal of separation science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.72
H-Index - 102
eISSN - 1615-9314
pISSN - 1615-9306
DOI - 10.1002/jssc.201600423
Subject(s) - metal organic framework , porosity , materials science , nanotechnology , catalysis , heterogeneous catalysis , porous medium , metal , solid phase microextraction , chemistry , organic chemistry , chromatography , mass spectrometry , adsorption , metallurgy , composite material , gas chromatography–mass spectrometry
Metal–organic frameworks are a new category of advanced porous materials with large surface areas and porosities, uniform pore sizes, tunable surface chemistry, and structural diversity. In combination with monoliths, they allow the fine tuning of desired interactions required in a variety of applications. This review article summarizes results of recent studies focused on synthetic strategies enabling incorporation of metal–organic frameworks in monolithic structures. A diverse array of applications including chromatographic separation, solid‐phase microextraction, sample enrichment, heterogeneous catalysis, and enzymatic catalysis are also described.