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Effect of competing binding modes on retention in chromatography and capillary electrophoresis. A theoretical consideration
Author(s) -
Asnin Leonid D.,
Nikitina Yuliya
Publication year - 2014
Publication title -
journal of separation science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.72
H-Index - 102
eISSN - 1615-9314
pISSN - 1615-9306
DOI - 10.1002/jssc.201301074
Subject(s) - capillary electrophoresis , chemistry , chromatography , formalism (music) , generalization , electrophoresis , mathematics , art , musical , mathematical analysis , visual arts
A mathematical formalism has been developed to describe equilibrium in a system involving a single selector and a selectand molecule capable of binding to this selector by different modes. The generalization of this model to a multiselector system has also been considered. Applications of the developed equations in chromatography and CE are discussed.