Premium
Solid‐phase microextraction based on polyaniline doped with perfluorooctanesulfonic acid coupled to HPLC for the quantitative determination of chlorophenols in water samples
Author(s) -
He Huan,
Zhuang Yuan,
Peng Ying,
Gao Zhanqi,
Yang Shaogui,
Sun Cheng
Publication year - 2014
Publication title -
journal of separation science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.72
H-Index - 102
eISSN - 1615-9314
pISSN - 1615-9306
DOI - 10.1002/jssc.201300788
Subject(s) - solid phase microextraction , chromatography , extraction (chemistry) , chemistry , polyaniline , divinylbenzene , detection limit , high performance liquid chromatography , pentachlorophenol , ionic strength , mass spectrometry , gas chromatography–mass spectrometry , aqueous solution , polymer , environmental chemistry , styrene , organic chemistry , copolymer , polymerization
A porous and highly efficient polyaniline‐based solid‐phase microextraction (SPME) coating was successfully prepared by the electrochemical deposition method. A method based on headspace SPME followed by HPLC was established to rapidly determine trace chlorophenols in water samples. Influential parameters for the SPME, including extraction mode, extraction temperature and time, pH and ionic strength procedures, were investigated intensively. Under the optimized conditions, the proposed method was linear in the range of 0.5–200 μg/L for 4‐chlorophenol and 2,4,6‐trichlorophenol, 0.2–200 μg/L for 2,4‐dichlorophenol and 2–200 μg/L for 2,3,4,6‐tetrachlorophenol and pentachlorophenol, with satisfactory correlation coefficients (>0.99). RSDs were <15% ( n = 5) and LODs were relatively low (0.10–0.50 μg/L). Compared to commercial 85 μm polyacrylate and 60 μm polydimethylsiloxane/divinylbenzene fibers, the homemade polyaniline fiber showed a higher extraction efficiency. The proposed method has been successfully applied to the determination of chlorophenols in water samples with satisfactory recoveries.