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Separation of parent homopolymers from diblock copolymers by liquid chromatography under limiting conditions of desorption 4. Role of eluent and temperature
Author(s) -
Berek Dušan
Publication year - 2010
Publication title -
journal of separation science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.72
H-Index - 102
eISSN - 1615-9314
pISSN - 1615-9306
DOI - 10.1002/jssc.201000501
Subject(s) - copolymer , desorption , limiting , chromatography , materials science , column chromatography , polymer , chemistry , organic chemistry , adsorption , mechanical engineering , engineering , composite material
Liquid chromatography under limiting conditions of desorption (LC LCD) enables fast, base‐line discrimination of both parent homopolymers from various diblock copolymers in one single step. The low molecular admixtures are fully separated, as well. General rules are discussed in detail for selection of mobile phases and temperature applied in LC LCD of block copolymers. Typical practical separation examples are presented. It is shown that both the composition of the well‐selected LC LCD mobile phase and the temperature of experiment may vary in a broad range without affecting the basics of method. This implies that the method is robust and user friendly.