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Rapid analysis of triazolopyrimidine sulfoanilide herbicides in waters and soils by high‐performance liquid chromatography with UV detection using a C 18 monolithic column
Author(s) -
RodríguezDelgado Miguel Ángel,
HernándezBorges Javier
Publication year - 2007
Publication title -
journal of separation science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.72
H-Index - 102
eISSN - 1615-9314
pISSN - 1615-9306
DOI - 10.1002/jssc.200600271
Subject(s) - chromatography , formic acid , high performance liquid chromatography , chemistry , calibration curve , detection limit , tap water , soil water , solid phase extraction , quantitative analysis (chemistry) , analytical chemistry (journal) , environmental science , environmental engineering , soil science , engineering
In this work, the simultaneous analysis of five triazolopyrimidine sulfoanilide herbicides (flumetsulam, florasulam, metosulam, cloransulam‐methyl, and diclosulam) by HPLC using UV detection and a C 18 monolithic column is proposed. The mobile phase which was composed of ACN, water, and formic acid was pumped at a high flow rate (5 mmL/min) providing an analysis time of all the compounds in less than 2.3 min. The LODs were in the low μg/L range ( i. e. between 60 μg/L for flumetsulam and 90 μg/L for florasulam) and the calibration curves showed good linearity ( R 2 > 0.9949). The method was applied to the analysis of these compounds in spiked mineral and tap waters and soils after an SPE preconcentration procedure using C 18 cartridges. Mean recovery values ranged between 35 and 110% for water samples providing LODs of the whole procedure in the low ng/L level, down to 280 ng/L, and between 77 and 92% for soil samples with LODs down to 9.38 μg/kg. This is the first time that this family of pesticides is simultaneously analyzed in both types of samples by HPLC and also using a monolithic column.