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Stationary and mobile phases in capillary electrochromatography (CEC)
Author(s) -
Jiskra Jan,
Claessens Henk A.,
Cramers Carel A.
Publication year - 2003
Publication title -
journal of separation science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.72
H-Index - 102
eISSN - 1615-9314
pISSN - 1615-9306
DOI - 10.1002/jssc.200301305
Subject(s) - capillary electrochromatography , electrochromatography , stationary phase , chemistry , phase (matter) , chromatography , organic chemistry
This review describes the state of the art of capillary electrochromatography (CEC). Properties of and interactions between stationary and mobile phases applied in CEC are described and discussed; developments in stationary phases, partly also monolithic stationary phases, are reviewed. Special attention is paid to the comparison of the behaviour of stationary and/or mobile phases under CEC versus HPLC conditions with respect to variables such as particle and pore size of the stationary phase, mobile phase composition, and temperature. These issues are discussed throughout the paper. A number of applications in CEC is presented as well.