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Evaluation of the feasibility of short‐term electrodialysis for separating naturally occurring fluoride from instant brick tea infusion
Author(s) -
Peng Chuanyi,
Liu Haifeng,
Qiao Huanhuan,
Luo Jing,
Liu Ximin,
Hou Ruyan,
Wan Xiaochun,
Cai Huimei
Publication year - 2019
Publication title -
journal of the science of food and agriculture
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.782
H-Index - 142
eISSN - 1097-0010
pISSN - 0022-5142
DOI - 10.1002/jsfa.10011
Subject(s) - electrodialysis , fluoride , electrolyte , chemistry , membrane , pulp and paper industry , inorganic chemistry , electrode , biochemistry , engineering
BACKGROUND Removing excessive naturally occurring fluoride from tea and/or infusions is difficult because the process has low efficiency and causes secondary pollution. In this study, a novel electrodialysis (ED) technology was developed. We examined the effect of crucial parameters (electrolyte concentration, operation voltage, ED duration and initial concentration of the tea infusion) on defluoridation performance using a highly efficient ion‐exchange membrane with five‐compartment cells. RESULTS The most effective ED system results were obtained at an electrolyte concentration of 10 g kg −1 and operating voltage of 20 V. Moreover, the fluoride removal capacity (10.70–66.93%) was highly dependent on the ED duration (1–15 min) and initial concentration of the tea infusion (0.5–10 g kg −1 ). The longer the ED duration and the lower the initial concentration, the higher was the defluoridation performance. During ED, limited loss of the main inclusions (total polyphenols, catechins, caffeine and selected ions) was observed. Furthermore, the D201 anion resin‐filled ED stack (0.5–5 g) and improvement of concentrate compartment electrolyte (≥5 times the dilute compartment electrolyte) in the ED system enhanced the defluoridation rate significantly. CONCLUSION ED is a potentially effective method that can be used for defluoridation in the deep processing of tea products. © 2019 Society of Chemical Industry