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Synthesis and Self‐Assembly Properties of New Surface‐Active 1‐Alkylimidazolium Ionic Liquids in Aqueous Media
Author(s) -
Adam Claudia G.,
Fortunato Graciela G.
Publication year - 2019
Publication title -
journal of surfactants and detergents
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.349
H-Index - 48
eISSN - 1558-9293
pISSN - 1097-3958
DOI - 10.1002/jsde.12260
Subject(s) - chemistry , counterion , ionic liquid , aggregation number , micelle , cationic polymerization , bromide , critical micelle concentration , gibbs free energy , alkyl , aqueous solution , pyrene , inorganic chemistry , organic chemistry , ion , thermodynamics , catalysis , physics
New cationic surface‐active ionic liquids (SAIL) were synthesized using 1‐alkylimidazolium cations [CnHim] ( n = 8, 10, 12, 14, and 16) with trifluoroacetate ([CF 3 CO 2 ]) and methanesulfonate ([CH 3 SO 3 ]) anions as counterions. Their self‐aggregation behavior in water was investigated using electrical conductivity and fluorescence measurements. Based on the obtained results, the critical micellar concentration (CMC), the degree of counterion dissociation, α , the Gibbs free energy of micelle formation, Δ G mic 0 , and the mean aggregation number ( N agg ) were determined. The analysis of these parameters indicates that these new SAIL exhibit certain improved properties with respect to traditional cationic surfactants. Furthermore, SAIL with [CF 3 CO 2 ] counterions exhibit lower CMC values than alkyltrimethylammonium bromide (C n TAB)‐type surfactants and their dialkylimidazolium counterparts with the same alkyl chain length. It was demonstrated that, in the studied SAIL, the hydrophobic probe pyrene resides deeper inside the palisade layer of the micelle and the estimated E T (30) polarity values of micellar pseudophase confirm this result. The abovementioned outcomes demonstrate that the 1‐alkylimidazolium cation is suitable to promote aggregation when it is accompanied by the appropriate counterions. Consequently, this contribution becomes a valuable first step toward the potential application of these compounds as a new class of “designed cationic surfactants.”