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Femtosecond degenerate four‐wave mixing of pyridine and its biologically relevant derivatives
Author(s) -
Frey H. M.,
Müller A.,
Leutwyler Samuel
Publication year - 2002
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.943
Subject(s) - degenerate energy levels , chemistry , pyridine , molecule , pyrazine , excitation , pyrimidine , femtosecond , ground state , molecular physics , mixing (physics) , computational chemistry , chemical physics , atomic physics , stereochemistry , physics , quantum mechanics , organic chemistry , laser
Time‐resolved degenerate four‐wave mixing experiments in the femtosecond time domain were employed to record the rotational ground‐state dynamics of the N‐heteroaromatic molecules pyridine, pyrimidine and pyrazine in the gas phase. Pyrimidine is an important molecular building block of several nucleic acid bases. The method records the time‐dependent change in third‐order polarization of a sample after coherent excitation. All three molecules are asymmetric tops in the oblate limit. From the analysis of the transients we obtained highly accurate averages of the two larger ground‐state rotational constants A and B . Copyright © 2002 John Wiley & Sons, Ltd.