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Phonons in isostructural compounds Cu x M 1− x (HCOO) 2 ·2H 2 O (M = Mn, Co, Ni, Zn, and Cd): a Raman scattering study
Author(s) -
Moura M. R.,
Paschoal C. W. A.,
Ayala A. P.,
Guedes I.,
Leyva A. G.,
Polla G.,
Vega D.,
Perazzo P. K.
Publication year - 2002
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.849
Subject(s) - isostructural , raman spectroscopy , formate , chemistry , raman scattering , crystallography , phonon , metal , inorganic chemistry , analytical chemistry (journal) , crystal structure , condensed matter physics , physics , optics , organic chemistry , catalysis
The Raman spectra of isostructural compounds Cu x M 1− x (HCOO) 2 ·2H 2 O (M = Mn, Co, Ni, Zn, and Cd) at room temperature are presented. The phonons observed were assigned on the basis of formate and water group vibrations and correlations with previous data reported for other formates. The influence of metal–guest ion substitution is discussed in the system Cu 0.53 Mn 0.47 (HCOO) 2 ·2H 2 O when Mn is replaced by Cd. Copyright © 2002 John Wiley & Sons, Ltd.