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Experimental and theoretical vibrational spectroscopic study on symmetric and asymmetric halo‐bridged complexes of palladium(II) and platinum(II)
Author(s) -
Kessenich E.,
Schulz A.,
Severin K.
Publication year - 2001
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.698
Subject(s) - palladium , chemistry , platinum , raman spectroscopy , infrared , crystallography , stereochemistry , catalysis , organic chemistry , physics , optics
The symmetric chloro‐bridged complexes [(Et 3 P) 2 PtCl(µ‐Cl)] 2 , [(Et 3 P) 2 Pt(µ‐Cl)] 2 2+ and [(C 3 H 5 )Pd(µ‐Cl)] 2 and the asymmetric complexes [(C 3 H 5 )Pd(µ‐Cl) 2 Pt(PEt 3 ) 2 ] + and [(C 3 H 5 )Pd(µ‐Cl) 2 Pt(PEt 3 )Cl] were studied by means of vibrational spectroscopy (infrared, Raman) and computational chemistry. Assignments of all normal modes associated with skeletal stretching are suggested and their displacement vectors are discussed. Copyright © 2001 John Wiley & Sons, Ltd.