Experimental and theoretical vibrational spectroscopic study on symmetric and asymmetric halo‐bridged complexes of palladium(II) and platinum(II) | Zendy

Kessenich E. | Zendy; Schulz A. | Zendy; Severin K. | Zendy

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Experimental and theoretical vibrational spectroscopic study on symmetric and asymmetric halo‐bridged complexes of palladium(II) and platinum(II)

Author(s) -

Kessenich E.,

Schulz A.,

Severin K.

Publication year - 2001

Publication title -

journal of raman spectroscopy

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.748

H-Index - 110

eISSN - 1097-4555

pISSN - 0377-0486

DOI - 10.1002/jrs.698

Subject(s) - palladium , chemistry , platinum , raman spectroscopy , infrared , crystallography , stereochemistry , catalysis , organic chemistry , physics , optics

The symmetric chloro‐bridged complexes [(Et 3 P) 2 PtCl(µ‐Cl)] 2 , [(Et 3 P) 2 Pt(µ‐Cl)] 2 2+ and [(C 3 H 5 )Pd(µ‐Cl)] 2 and the asymmetric complexes [(C 3 H 5 )Pd(µ‐Cl) 2 Pt(PEt 3 ) 2 ] + and [(C 3 H 5 )Pd(µ‐Cl) 2 Pt(PEt 3 )Cl] were studied by means of vibrational spectroscopy (infrared, Raman) and computational chemistry. Assignments of all normal modes associated with skeletal stretching are suggested and their displacement vectors are discussed. Copyright © 2001 John Wiley & Sons, Ltd.

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