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Identifying the polymorphs of serpentine with micro‐Raman spectroscopy: Clear separation in biaxial plots
Author(s) -
Kashima Aruto,
Urashima Shuhei,
Yui Hiroharu
Publication year - 2022
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.6355
Subject(s) - raman spectroscopy , materials science , crystallography , spectroscopy , olivine , crystal (programming language) , crystal structure , quartz , amorphous solid , molecular vibration , analytical chemistry (journal) , mineralogy , chemistry , optics , composite material , physics , chromatography , quantum mechanics , computer science , programming language
Serpentine, Mg 3 Si 2 O 5 (OH) 4 , is a phyllosilicate mineral having several polymorphs, that is, antigorite, chrysotile, lizardite, and polygonal. Because the crystal structure is dependent on thermodynamic environment where serpentine was produced, it has been desired for the polymorphs to be distinguished for geoscientific investigation. While crystal structures are analyzed by X‐ray crystallography in many cases, it is difficult to apply the X‐ray technique to small and/or non‐uniform samples. In the present study, we achieved to unambiguously determine the serpentine's polymorphs with microscopic Raman spectroscopy. Among various Raman‐active vibrational modes, we focused on the SiOSi symmetric stretching mode and bending vibration of SiO 4 units because layer structure of SiO 4 tetrahedral sheets (T‐sheets) alters with the crystal structure. With the peak wavenumbers determined with subpixel accuracy, the polymorphs were clearly separated in biaxial plots of the peak wavenumbers. As a result, we succeeded in distinguishing lizardite and polygonal serpentine, which were believed to be indistinguishable from Raman spectra, for the first time. Because microscopic Raman spectroscopy is nondestructive method that requires neither large single crystals nor any pretreatment of samples, it is applicable to small (<1 mm), fragile, rare, and/or heterogeneous samples. This feature advantages our technique for the investigation on non‐uniform and a trace amount of serpentines in terrestrial mantle rocks from seafloor and in meteorites from asteroids carrying complex histories of their formation and aqueous alteration.