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228‐nm quadrupled quasi‐three‐level Nd:GdVO 4 laser for ultraviolet resonance Raman spectroscopy of explosives and biological molecules
Author(s) -
Bykov Sergei V.,
Roppel Ryan D.,
Mao Michael,
Asher Sanford A.
Publication year - 2020
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.5999
Subject(s) - raman spectroscopy , laser , resonance raman spectroscopy , resonance (particle physics) , ultraviolet , excited state , excitation , spectroscopy , chemistry , materials science , photon upconversion , optoelectronics , optics , atomic physics , luminescence , electrical engineering , quantum mechanics , engineering , physics
We describe a new compact diode‐pumped solid‐state frequency quadrupled quasi‐three‐level neodymium‐doped gadolinium vanadate (Nd:GdVO 4 ) laser that generates ~50 mW of 228‐nm quasi‐continuous wave light as ns pulses at a tunable kilohertz repetition rate. We developed two generations of this laser. The first generation has a high duty cycle and a tunable repetition rate. The second generation is optimized for maximum output power. We utilize these new lasers to measure ultraviolet resonance Raman (UVRR) spectra of many important chromophores that absorb in deep ultraviolet (UV). We demonstrate the utility of this excitation by measuring the 228‐nm absolute differential Raman cross sections of explosives, peptides, aromatic amino acids, and DNA/RNA nucleotides. Deep UV excitation at 228 nm occurs within the π → π* electronic transitions of these molecules. The 228‐nm resonance excitation enhances the Raman intensities of vibrations of NO x groups, peptide bonds, aromatic amino acid side chains, and DNA/RNA nucleotides. The measured 228‐nm UVRR cross sections of these molecules are 10 3 –10 4 fold greater than those excited in the visible spectral region. These new lasers should be of great interest for UVRR spectroscopy and for other applications that benefit from compact, high average power deep UV laser light sources with low peak powers.