Accurate wavenumber measurements for the  S  0 (0),  S  0 (1), and  S  0 (2) pure rotational Raman lines of D 2 | Zendy

Martínez Raúl Z. | Zendy; Bermejo Dionisio | Zendy; Wcisło Piotr | Zendy; Thibault Franck | Zendy

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Accurate wavenumber measurements for the S 0 (0), S 0 (1), and S 0 (2) pure rotational Raman lines of D 2

Author(s) -

Martínez Raúl Z.,

Bermejo Dionisio,

Wcisło Piotr,

Thibault Franck

Publication year - 2019

Publication title -

journal of raman spectroscopy

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.748

H-Index - 110

eISSN - 1097-4555

pISSN - 0377-0486

DOI - 10.1002/jrs.5499

Subject(s) - raman spectroscopy , wavenumber , quantum number , ab initio quantum chemistry methods , ab initio , atomic physics , physics , chemistry , quantum mechanics , molecule

We present accurate measurements for the wavenumbers of the S 0 (0), S 0 (1), and S 0 (2) pure rotational Raman lines in D 2 . Our measurements improve the accuracy of the previously available experimental data by an order of magnitude. They also show complete agreement with the state‐of‐the‐art ab initio calculations of the D 2 rotational splitting, which include both relativistic and Quantum electrodynamics (QED) corrections.

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