High‐resolution stimulated Raman spectroscopy and analysis of the  ν  2  and  ν  3  bands of C 2 H 4 | Zendy

Ballandras A. | Zendy; Cirtog M. | Zendy; Loroño M. A. | Zendy; Bourgeois M.T. | Zendy; Rotger M. | Zendy; Bermejo D. | Zendy; Martínez R. Z. | Zendy; Doménech J. L. | Zendy; Boudon V. | Zendy

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High‐resolution stimulated Raman spectroscopy and analysis of the ν 2 and ν 3 bands of C 2 H 4

Author(s) -

Ballandras A.,

Cirtog M.,

Loroño M. A.,

Bourgeois M.T.,

Rotger M.,

Bermejo D.,

Martínez R. Z.,

Doménech J. L.,

Boudon V.

Publication year - 2013

Publication title -

journal of raman spectroscopy

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.748

H-Index - 110

eISSN - 1097-4555

pISSN - 0377-0486

DOI - 10.1002/jrs.4328

Subject(s) - raman spectroscopy , root mean square , formalism (music) , analytical chemistry (journal) , spectral line , standard deviation , resolution (logic) , infrared , chemistry , high resolution , physics , mathematics , optics , geology , statistics , quantum mechanics , remote sensing , art , musical , chromatography , artificial intelligence , computer science , visual arts

The high‐resolution stimulated Raman spectra of the ν 2 and ν 3 bands of C 2 H 4 have been recorded and analyzed separately by means of the tensorial formalism developed in Dijon and Reims for X 2 Y 4 asymmetric‐top molecules. For the ν 2 band, a total of 191 lines were assigned and fitted. We obtained a global root mean square deviation of 1.86 × 10 − 3 cm − 1 . For the ν 3 band analyzed in interaction with the ν 6 infrared band, a total of 185 lines were assigned and fitted. We obtained a global root mean square deviation of 1.29 × 10 − 3 cm − 1 . Both analyses lead to very satisfactory synthetic spectra. Copyright © 2013 John Wiley & Sons, Ltd.

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